ISSN:
1434-4475
Keywords:
Diphenyl-chloro-organylamino-silanes
;
Silanes asymmetrically substituted bis(organylamino)
;
Thermal rearrangement silanes]
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The title compoundsR 2Si(NHR 1) (NHR 2) (B) were prepared according to Equ. (2) and (3) and via formerly unknown diphenyl-chloro-organylaminosilanes (A) as intermediates. The complex course of formation ofB in competition withR 2Si (NHR 1)2 (C) andR 2Si(NHR 2)2 (D) (Scheme 1, Equ. (4)–(7), Table 2) was investigated in detail. Results of thermal rearrangement ofB are given in Table 5. Five novelA and six novelB compounds are confirmed by properties, elemental and structural data (Tables 1, 3 and 4).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00910955
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