ISSN:
0749-1581
Keywords:
Brucine Gibberellic acid
;
Gradient-selective COSY 2D correlation
;
Double-quantum filter
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
High-quality gradient-selective COSY spectra were recorded at 300 MHz for brucine and gibberellic acid and double-quantum filtered gradient-selective COSY spectra for brucine, using a single-frequency, high-resolution 1H probe modified by the addition of an unshielded z-gradient coil set. Data were efficiently recorded using buffered acquisition with a single transient per increment in 1t, in times much lower than those required for phase-cycled COSY, and with no loss of information. Gradient-selective COSY90, COSY45 and long-range COSY45 experiments, and the correlations leading to chemical shift assignments for gibberellic acid, are reported.
Additional Material:
6 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260300813
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