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  • Michael addition  (1)
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  • Electronic Resource  (1)
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    Electronic Resource
    Electronic Resource
    Zur Synthese von 4-Aryl-5,6-dihydro-benzo[h]chinolinen (1979)
    Springer
    Monatshefte für Chemie 110 (1979), S. 115-119 
    Details
    ISSN: 1434-4475
    Keywords: Benzo[h]quinolines ; Mechanism ; Michael addition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A new route to the benzo[h]quinoline system3 byMichael-addition of malononitrile to 2-arylidene-1-tetralones1 is presented. The mechanism of this reaction is elucidated by isolation of the intermediate 4H-naphtho[1,2—b]-pyrane2 and its reaction to3. The reaction is proposed to be a sequence of addition, cyclisation,Dimroth-rearrangement and disproportionation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00903753
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