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  • Electronic Resource  (6)
  • Organic Chemistry  (6)
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  • Electronic Resource  (6)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1981 (1981), S. 1198-1206 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Acylations of Alkyl Thiocyanates.Alkyl thiocyanates 3 react with acyl chloride/SbCl5 to give N-benzoyl-C-(methylthio)nitrilium hexachloroantimonate(V) (4) or the 2-aryl(alkyl)-4,6-bis(alkylthio)-1,3,5-oxadiazinium hexachloroantimonates(V) 6. Reactions of 6 with water yield the isothiourea derivatives 7 or the thioallophanic acid derivatives 15, with amines the derivatives 8 and 17 of guanidine are formed.
    Notes: (Alkyl)thiocyanate 3 reagieren mit Acylchlorid/SbCl5 zu N-Benzoyl-C-(methylthio)nitrilium-hexachioroantimonat(V) (4) oder zu den 2-Aryl(Alkyl)-4,6-bis(alkylthio)-1,3,5-oxadiazinium-hexachloroantimonaten(V) 6. Die Umsetzungen von 6 mit Wasser ergeben die Isothioharnstoffderivate 7 oder die Thioallophansäurederivate 15, mit Aminen bilden sich die Guanidinderivate 8 und 17.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1988 (1988), S. 729-731 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Reactions of 2-Aryl-4,6-bis(methylthio)-1,3,5-thiadiazinium Salts2-Aryl-4,6-bis(methylthio)-1,3,5-thiadiazinium salts 2 are synthesized. Reactions of 2 with water or hydrogen sulfide yield derivatives of dithioallophanic acid 3 or 5-aryl-2-methylthio[1,2,4]-dithiazolo[1,5-b][1,2,4]dithiazoles 8. With amines the derivatives 4 and 5 of guanidine are formed.
    Notes: 2-Aryl-4,6-bis(methylthio)-1,3,5-thiadiazinium-Salze 2 werden synthetisiert. Durch Umsetzungen von 2 mit Wasser oder Schwefelwasserstoff erhält man Dithioallophansäurederivate 3 oder 5-Aryl-2-methylthio[1,2,4]dithiazolo[1,5-b][1,2,4]dithiazole 8. Mit Aminen bilden sich Guanidinderivate 4 und 5.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1990 (1990), S. 307-309 
    ISSN: 0170-2041
    Keywords: Bis(1,3,5-oxadiazinium)salts, dicationic ; 1,3,5-Oxadiazine ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Reactions of Methyl Thiocyanate with Diacyl DichloridesDiacyl dichlorides react with methyl thiocyanate in the presence of SbCl5 to give dicationic bis(1,3,5-oxadiazinium) salts 1. Hydrolysis of 1 yields derivatives of N,N′-bis[(methyl-thiocarbonyl)carbamoyl] diamides 2.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1985 (1985), S. 1874-1881 
    ISSN: 0170-2041
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Reactions of 2-Aryl(Alkyl)-4,6-bis(alkylthio)-1,3,5-oxadiazinium Salts with Nucleophiles2-Aryl(Alkyl)-4,6-bis(alkylthio)-1,3,5-oxadiazinium salts 2 react with ammonia and amidines to give the derivatives 6, 7, and 8 of 1,3,5-triazine. Reactions of 2 with hydrazine or hydrogen sulfide yield S-methyl N-(5-aryl-4H-1,2,4-triazol-3-yl)thiocarbamidates 5 or S-methyl N-(5-aryl-3H-1,2,4-dithiazol-3-ylidene)thiocarbamidates 9, respectively.
    Notes: 2-Aryl-(Alkyl-)-4,6-bis(alkylthio)-1,3,5-oxadiaziniumsalze 2 reagieren mit Ammoniak und Amidinen zu den 1,3,5-Triazinderivaten 6, 7 und 8. Durch Umsetzungen von 2 mit Hydrazin oder Schwefelwasserstoff erhält man N-(5-Aryl-4H-1,2,4-triazol-3-yl)thioarbamidsäure-S-methylester 5 bzw. N-(5-Aryl-3H-1,2,4-dithiazol-3-yliden)thiocarbamidsäure-S-methylester 9.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1975 (1975), S. 1025-1027 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Note on the Reaction of Phenyl Isothiocyanate with Antimony PentachloridePhenyl isothiocyanate (1) reacts with antimony pentachloride to give N-(2-benzothiazolyl)-N- (pheny1)thiocarbamoyl chloride (2). Interaction between 2 and amines yields new derivatives of thiourea.
    Notes: Phenylisothiocyanat (1) reagiert mit Antimon(V)-chlorid zu N-(2-Benzthiazolyl)-N-(phenyl)- thiocarbamoylchlorid (2). Durch Umsetzung mit Aminen erhält man aus 2 neue Thioharnstoffderivate.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1978 (1978), S. 1704-1706 
    ISSN: 0075-4617
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Note on the Reaction of Alkyl Thiocyanate with OxalylchlorideAlkyl thiocyanates 1 react with oxalyl chloride in presence of BF3 to give N,N'-bis(methylthio-chloromethylene)oxamide (2) or N-(ethylthiochloromethylene)oxamoyl chloride (3). Interaction between 2 and aniline yields new derivatives 5 and 6 of triazepine and imidazoline, respectively.
    Notes: Alkylthiocyanate 1 reagieren mit Oxalyldichlorid in Gegenwart von BF3 zu N,N'-Bis(methylthio-chlormethylen)oxamid (2) oder zu N-(Ethylthiochlormethylen)oxamoylchlorid (3). Durch Umsetzung von 2 mit Anilin erhält man neue Triazepin- und Imidazolindrivate 5 bzw. 6.
    Type of Medium: Electronic Resource
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