ISSN:
0360-6376
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Three types of isopropenylmetallocene monomers were synthesized and subjected to polymerization and copolymerization by cationic initiators; (1) isopropenylferrocene (IF); (2) (η5-isopropenylcyclopentadienyl)dicarbonylnitrosylmolybdenum (IDM); and (3) 1,1′-diisopropenylcyclopentadienylstannocene (DIS), and related derivatives of each. IF was synthesized by a three-step procedure involving the acetylation of ferrocene, conversion of the latter to 2-ferrocenyl-2-propanol, and dehydration of the carbinol. IF was homopolymerized under various cationic initiation conditions, but only low molecular weight homopolymers were obtained. Copolymerization of IF with styrene and with p-methoxy-α-methylstyrene also gave only low molecular weight products. The formation of only low molecular weight polymers in all polymerization reactions is believed to result from the effect of the unusually high stability of ferrocenyl carbenium ions on its propagation reaction. The observed polymerization behavior of α-trifluoromethylvinylferrocene is in accord with this conclusion. IDM and DIS did not form polymeric products under cationic conditions, although copolymers could be obtained for each of these monomers and styrene with a free radical polymerization initiator (AIBN).
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1985.170230612
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