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  • Electronic Resource  (24)
  • Polymer and Materials Science  (24)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 1459-1464 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dynamic mechanical properties of cured epoxy resin have been studied in which copper powder treated or untreated with azole compounds was used as fillers. The untreated fillers do not shift the glass transition temperature of the matrix polymer of the composites, whereas the storage modulus rises with increasing content of fillers. The application of azole compounds as coupling agents, which could react with both copper and epoxy resin, extended the polymer-filler interactions. The composite filled with copper powder treated with benzotriazole shows a strong reinforcement effect and high resistance to moisture.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 987-991 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A flat-spring supported sample technique has been developed for studying the dynamic mechanical properties of a polymer in all its mechanical states, especially for materials with insufficient tensile strength for tensile mode test. The results obtained by this new technique show good agreement with the data from tensile mode tests for poly(ethylene terephthalate) and polystyrene. A high crystallization rate in temperature region 110-160°C for a quenched poly(ethylene terephthalate) and a secondary relaxation at the temperature of 100°C above Tg for a monodispersed polystyrene with a molecular weight of 3 × 105 could be measured quantitatively by the flat-spring supported polymer technique. This is an important improvement over the existing supported sample techniques.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 1087-1092 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Dynamic mechanical analysis, using a flat-spring to support the sample, was conducted to study the properties of polyurethane ionomers prepared from poly(epoxy chloropropane) as polyol. The effects of the soft segment length and ionization level on the properties were studied. For the unionized polyurethane, the soft and hard segments had good compatibility and little phase separation was found due to the high polarity of the polyol. For the shorter hard segment ionomers, as the ionization level increased, the matrix Tg rose due to the increase in the compatibility of hard and soft segments. For the longer ionized hard segment ionomers, the aggregating tendency of ion pairs enhanced phase separation. Quenching or annealing the samples showed that clusters existing in bulk materials did not dissociate below the degradation temperature and multiplets can dissociate or transform to clusters below 150°C.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A two-component coupling agent layer consisting of polybenzimidazole and 4 aminophenyl disulfide showed better anticorrosive performance and higher adhesive strength for copper and resins than did each single component even at high temperature. © 1995 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 2633-2646 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The reinforcement mechanism of polyester tire cord was studied by Fourier-transform infrared spectroscopy using various model compounds. Three model compounds representing the main chain of polyester and the terminal groups, namely carboxylic acid and hydroxyl groups, were used. Chemical reactions between these polyester models and an epoxy functional silane coupling agent were studied qualitatively as well as quantitatively. Among the many possible reactions, the reaction between the carboxylic acid and epoxy group was found to proceed readily. Kinetic studies of the major reactions also show quantitative differences in their activation energies as well as the rate constants. Based on the quantitative studies, we have estimated the expected rate of interfacial reaction at the heat treating temperature of polyester tire cord.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 153 (1987), S. 89-94 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Aus Kohlegängen wurde Füllmaterial für PVC-Compounds hergestellt. FT-IR Untersuchungen zeigen, daß diese Gänge aromatische Komponenten mit phenolischen Gruppen enthalten. Die Verwendung der Gänge als Füllstoff in Hart-PVC-Compounds führt zu Materialien mit guten mechanischen Eigenschaften, hoher Hitzeund chemischer Beständigkeit und niedrigen Kosten.
    Notes: Fillers for PVC compounds have been made from coal gangue. FT-IR studies show that it contains aromatic components with phenolic groups. Application of gangue as a filler in rigid PVC compounds gives rise to materials of good mechanical properties, high heating and chemical resistance, and lower cost.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 151 (1987), S. 85-93 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurden chemische Reaktionen der Epoxy-Gruppe von (3-Glycidyloxypropyl)-trimethoxysilan in wässriger Lösung mit Hilfe der Fourier Transform-Infrarotspektroskopie (FT-IR) untersucht. Es zeigte sich, daß die Epoxygruppe mit der Silanolgruppe unter Bildung einer SiOCC-Struktur, gleichzeitig aber auch mit Wasser reagiert. Die Kinetik dieser Reaktionen wurde untersucht.
    Notes: Chemical reactions of the functional epoxy group of γ-glycidoxypropyltrimethoxysilane in aqueous solution have been studied by Fourier transform infrared spectroscopy (FT-IR). It was found that the epoxy group reacts with the silanol group forming a SiOCC structure, and concurrently reacts with water. The kinetics of these reactions were studied.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 15 (1994), S. 99-102 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Macromolecular Rapid Communications 15 (1994), S. 719-722 
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1022-1336
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Two polyimides having the same backbone chemical structure and different pendant side groups at the 2- and 2′-positions of the diamine, the six methylene units capped with 4-cyanobiphenyl end groups and trifluoromethyl, were synthesized (6FDA-6CBO and 6FDA-PFMB). Surface-enhanced Raman scattering and surface optical second harmonic generation measurements show that after rubbing the major change in 6FDA-PFMB surface appears in the orientation of the dianhydride, which was originally planar, but becomes tilted with respect to the surface plane. In the case of 6FDA-6CBO, rubbing also causes the originally planar 4-cyanobiphenyls to tilt away from the surface and assume an azimuthally anisotropic distribution.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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