ISSN:
1434-1948
Keywords:
Porphyrazines
;
Fullerenes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
X-ray structural analysis of octakis(dimethylamino)porphyrazinato-metallo(II)·[60]fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a Ci symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
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