ISSN:
1432-2234
Keywords:
Gas phase acidity
;
Proton affinity
;
Carbanions
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract It has been shown, by double zeta quality ab initio MO calculations, that, in the gas phase, a CH bond adjacent to sulphur is more acidic than a CH bond adjacent to oxygen. This trend is in agreement with experimental observations in solution.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00527562
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