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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 113 (1982), S. 381-388 
    ISSN: 1434-4475
    Keywords: Digermoxanes ; Disiloxanes ; Methoxysilanes ; Odour ; Sila-perfumes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The odour of the formerly unknown compounds benzyldimethylmethoxysilane2 a (flower-honey like with a minty component; intensity middle), bis(benzyl)tetramethyldisiloxane4 a (flowerlike; very weak) and bis(benzyl)tetramethyldigermoxane9 (almond-soapy like; relatively strong) was registered and compared with related compounds (for example benzyldimethylmethoxymethane5 a, camphor-radish like). Information is given on preparation and analytical and structural investigation of several methoxysilanes and disioxanes with benzyl and phenethyl groups (compare equations and experimental part).
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Monatshefte für Chemie 116 (1985), S. 693-700 
    ISSN: 1434-4475
    Keywords: Sila-perfumes ; Silacyclohexanon-2 ; Sila-β-ionone
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Preparation of sila-β-ionone (14) was possible by a novel route with yields nearly 5 times higher than before1, with the formerly unknown 1,1,3-trimethyl-1-silacyclohexanone-2 (6) as a key substance. The nine reaction steps may be seen from Scheme 1. 2-Ethinyl-1,1,3-trimethyl-1-silacyclohexan-2-ol (7) could not be dehydrated to give the analogous silacyclohexene derivative9. But dehydration was successful in the case of 2-(1-butin-3-ol) substituents; here only the ring but not the chain hydroxyl group was eliminated.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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