ISSN:
1434-4475
Keywords:
Sila-perfumes
;
Silacyclohexanon-2
;
Sila-β-ionone
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Preparation of sila-β-ionone (14) was possible by a novel route with yields nearly 5 times higher than before1, with the formerly unknown 1,1,3-trimethyl-1-silacyclohexanone-2 (6) as a key substance. The nine reaction steps may be seen from Scheme 1. 2-Ethinyl-1,1,3-trimethyl-1-silacyclohexan-2-ol (7) could not be dehydrated to give the analogous silacyclohexene derivative9. But dehydration was successful in the case of 2-(1-butin-3-ol) substituents; here only the ring but not the chain hydroxyl group was eliminated.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00809147
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