ISSN:
0894-3230
Keywords:
Chemistry
;
Theoretical, Physical and Computational Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Cyclic voltammetry of 1-nitroso-2-naphthol in the potential region 0 to 1·0 V vs Ag/AgCl using glassy carbon and platinum electrodes shows a reversible redox couple. The electrode process is diffusion controlled and corresponds to an EC mechanism. The one-electron oxidation product, an iminoxyl radical, is characterized by a triplet ESR signal at g = 2·0067 further split by three ring hydrogens. This radical is unusually long-lived, with half-life times of 150 s in water and 3600 s in acetonitrile.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
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