ISSN:
1572-879X
Schlagwort(e):
vanadylpyrophosphate
;
butane oxidation
;
maleic anhydride
;
catalyst
;
pairing of vanadyl groups
;
ESR spectroscopy
;
magnetic susceptibility
;
Curie–Weiss behaviour
;
Curie constant
;
Weiss temperature
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract ESR and magnetisation experiments have identified a new type of antiferromagnetic pairing of vanadyl groups in the butane oxidation catalyst vanadylpyrophosphate. This pairing is an order of magnitude weaker than the coupling predominantly found in crystalline (VO)2P2O7.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1023/A:1019096409678
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