ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The central phenylene ring of 1,4-bis(3,4-dimethylphosphol-1-yl)benzene undergoes [1,5] shifts around both phospholyl rings above 150°C to give 1,4-bis(3,4-dimethyl-5H-phosphol-2-yl)benzene, which can be trapped by tolane, [CpFe(CO)2]2, or Mn2 (CO)10 to yield the corresponding bis-1-phosphanor-bornadiene, bis-phosphaferrocene, or bis-phosphacymantrene respectively.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520010211
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