ISSN:
1600-5759
Source:
Crystallography Journals Online : IUCR Backfile Archive 1948-2001
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
Notes:
A combinatorial chemistry approach has been used to synthesize an array of Schiff bases, five of which, namely N-[(E,2E)-3-(4-methoxyphenyl)-2-propenylidene]-3-nitroaniline, C16H14N2O3, (1a), N-[(E,2E)-3-(4-methoxyphenyl)-2-propenylidene]-4-nitroaniline, C16H14N2O3, (2a), N-{(E,2E)-3-[4-(dimethylamino)phenyl]-2-propenylidene}-3-nitroaniline, C17H17N3O2, (1b), N-{(E,2E)-3-[4-(dimethylamino)phenyl]-2-propenylidene}-4-nitroaniline, C17H17N3O2, (2b), and N-{(E,2E)-3-[4-(dimethylamino)phenyl]-2-propenylidene}-2-methyl-4-nitroaniline, C18H19N3O2, (3b), have been structurally characterized. A stack structure is observed for (1a) and (1b) in the crystal phase. Experimental and calculated molecular structures are discussed for these compounds which belong to a chemical class having potential applications as non-linear optical materials.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1107/S0108270100002845
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