Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
84 (1986), S. 3638-3646
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Calculations of photoionization cross sections and photoelectron angular distributions have been performed for all occupied orbitals of CF4 using the multiple-scattering model. Results are compared with very recent experiments which employ synchrotron radiation to measure these quantities, namely the measurements of Truesdale et al. for the carbon K shell, and measurements of Carlson et al. and Novak et al. for the five outermost valence levels. The calculations predict intense shape resonances below 3 eV in continua of a1 and t2 final state symmetry. Qualitative agreement is attained on comparing much of the theory with experiment, notably the five outer valence levels, which serves to establish a one-electron picture of the photoionization dynamics of CF4.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.450202
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