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  • Electronic Resource  (4)
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  • Electronic Resource  (4)
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  • 1
    Electronic Resource
    Electronic Resource
    Oxford UK : Blackwell Science Ltd
    Sedimentology 45 (1998), S. 0 
    ISSN: 1365-3091
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Geosciences
    Notes: Geologists commonly purport that successions of strata show one or more thickening and/or thinning upward trends, often prompting colleagues to argue that the `trends' are subjectively identified, unproven or nonexistent. Parametric and randomization tests are proposed to evaluate the null hypothesis of random succession against a variety of alternative postulates of trend. In place of test statistics in vogue that merely compare each bed thickness with that of the beds immediately above and below it, test statistics based on Kendall's S and Tau that make sequence-wide (or subsequence-wide) comparisons of bed thicknesses are advocated. The test statistic used and the exact form of the test depends on the alternative model considered: against the alternative of a single thickening (and/or thinning) upward trend, Kendall's S or equivalently Kendall's Tau are recommended. These statistics make pair-wise comparisons of beds, comparing bed thicknesses with their positions in the vertical sequence. Against the alternative of trends in g subsequences recognized a-priori, e.g. those separated by breaks such as thick sequences of hemipelagic shale, test statistics proposed include: the weighted sum of the g Tau coefficients calculated for the individual subsequences (if subsequences are alleged to be all thickening or all thinning upward), and the weighted sum of the absolute value, or square, of the Tau coefficients (if subsequences are alleged to include both thickening and thinning upward patterns). Tests can indicate that a sequence has one or more subsequences which are nonrandom, but it will not indicate which. To test each subsequence for significance, test each of g subsequences at a level of significance = α/g, thus achieving an overall, sequence-wide, level of significance = α. Against the alternative g subsequences recognized post-hoc, i.e. purely on the basis of observed thickness patterns, a family of test statistics are proposed, each equal to the maximum value of the appropriate test statistic (defined for subsequences recognized a-priori) that is attainable by partitioning the total sequence of beds into 1, 2,…. up to g subsequences. Both same-type and mixed subsequences alternatives arise. Each test proposed is applied to several different sequences, mostly turbidites.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] 146Sm decays to 142Nd with a half-life of 103 Myr. The presence of 'live' 146Sm in the early Solar System is well established on the basis of several achondrite mineral isochrons; the initial abundance of 146Sm is now established4'9-14 at 146Sm/144Sm = 0.0078 ±0.0010 at 4,566 Myr. Because ...
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 20 (1988), S. 9-25 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Vinylacetylene and 2-butyne mixtures were pyrolyzed at 350-450°C in the absence and presence of O2 and NO. The major product of the reaction is a polymer, but o-xylene is also produced and was studied as the species of interest. The C8H10 formation rate is first-order in C4H4 and C4H6. The rate coefficient is best fitted by \documentclass{article}\pagestyle{empty}\begin{document}$$\log {\rm [}k{\rm (C}_{\rm 8} {\rm H}_{{\rm 10}}),{\rm M}^{{\rm -1}}\, {\rm s}^{{\rm - 1}}] = (4.33 \pm 0.58) - (80.1 \pm 7.4)/2.3RT$$\end{document} though it is not inconsistent with \documentclass{article}\pagestyle{empty}\begin{document}$$\log {\rm [}k{\rm (C}_{\rm 8} {\rm H}_{{\rm 10}}),{\rm M}^{{\rm - 1}}\, {\rm s}^{{\rm - 1}}] = (7.93) - (125.9)/2.3RT$$\end{document} where R is the ideal gas constant in kJ/mol-K. O-xylene formation occurs by two processes: a concerted molecular mechanism (⋍67%) and a singlet diradical mechanism (⋍33%).
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 21 (1989), S. 175-191 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 2-Methylbut-1-ene-3-yne and Propyne mixtures were pyrolyzed at 350-450°C in the absence and presence of O2 and NO. The major product of the reaction is a polymer, but m-xylene and p-xylene are also produced and were studied as the species of interest. The C8H10 formation rate is first-order in C3H4 and C5H6. The rate coefficient is best fitted by \documentclass{article}\pagestyle{empty}\begin{document}$$\log [k({\rm C}_{\rm 8} {\rm H}_{{\rm 10}}),M^{ - 1} s^{ - 1}] = (11.2 \pm 1.0) - (166 \pm 13)/2.3RT$$\end{document} though it is not inconsistent with \documentclass{article}\pagestyle{empty}\begin{document}$$\log [k({\rm C}_{\rm 8} {\rm H}_{{\rm 10}}),M^{ - 1} s^{ - 1}] = (8.17) - (125.9)/2.3RT$$\end{document} where R is the ideal gas constant in kJ/mol-K. Experiments in the presence of NO show that m-xylene and p-xylene formation occur by two processes: a concerted molecular mechanism (≃ 41%) and a singlet diradical mechanism (≃ 59%).
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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