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  • 1
    Electronic Resource
    Electronic Resource
    Synthesis of mainly linear poly(dichlorophenylene oxide)s by thermal polymerization in solution (1992)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 193 (1992), S. 619-625 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Thermal decomposition of bis(4-bromo-2,6-dichlorophenoxo)-(N,N,N',N'-tetramethylethy-lenediamiene)copper(II) complex in toluene, bis(4-bromo-2,6-dichlorophenoxo)(N,N-dimethyl-formamide)copper(II) complex in N,N-dimethylformamide and bis(4-bromo-2,6-dichlorophenoxo)(dimethyl sulfoxide)copper(II) complex in dimethyl sulfoxide was achieved at 70°C. 4-Bromo-2,6-dichlorophenol derivatives prefer 1,4-addition to 1,2-addition, leading to highly linear polymers irrespective of the substituted ligands. The complexes were characterized by IR spectroscopy and C, H, N elemental analysis. The characterization of the synthesized polymers were achieved by 1H NMR, 13C NMR and IR spectroscopy. The highest polymer yield was obtained from the decomposition of bis(4-bromo-2,6-dichlorophenoxo)(N,N,N',N'-tetramethyl-ethylenediamine)copper(II) complex.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1992.021930307
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  • 2
    Electronic Resource
    Electronic Resource
    Thermal polymerization of bis(trihalophenoxo)copper(II) complexes in excess dimethylformamide and dimethyl sulfoxide as ligands (1989)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 190 (1989), S. 1843-1853 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Thermal decomposition of bis(trihalophenoxo)copper(II) complexes was achieved at 50°C in dimethylformamide or dimethyl sulfoxide. The resulting polymers, poly(oxydihalophenylene)s (2), were characterized by FTIR, 1H NMR and 13C NMR spectroscopy and by differential scanning calorimetry. The molecular weights were determined by the vapour pressure method. Tribrominated phenol derivatives prefer 1,4-substitution, whereas with trichlorophenol derivatives 1,2-and 1,4-substitutions take place at equal rates in either solvent.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1989.021900810
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Complex-radical terpolymerization of phenanthrene, maleic anhydride, and trans-stilbene (1995)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 7-13 
    Details
    ISSN: 0887-624X
    Keywords: radical terpolymerization ; charge transfer complexes ; phenanthrene ; maleic anhydride ; trans-stilbene ; thermal stability ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The radical terpolymerization of the donor-acceptor-donor monomer system, phenanthrene (P) - maleic anhydride (M) - trans-stilbene (S), was studied. These monomers are known to be nonhomopolymerizable. The terpolymerization was carried out in p-dioxane and/or toluene at 70°C in the presence of benzoyl peroxide used as the initiator. P and S were found to form charge transfer complexes (CTC) with M in p-dioxane at 35°C. The results obtained are discussed in terms of the free monomer and complex propagation models. It is shown that terpolymerization is carried out at a stage close to binary copolymerization of two complexomers. The reactivity ratio of P … M and S … M complexes was estimated by the Kelen-Tüdös method. Absorbance ratios at 1770 cm-1 (vC=0 of anhydride group), 764 cm-1 (δCH in monosubstituted benzene of S), and 820 cm-1 (δCH in disubstituted benzene of P) as a function of terpolymer composition were established. P - M - S terpolymers are shown to have high thermal stabilities. © 1995 John Wiley & Sons, Inc.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pola.1995.080330102
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  • 4
    Electronic Resource
    Electronic Resource
    Thermal polymerization of bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex in solution and in solid state (1998)
    Weinheim : Wiley-Blackwell
    Macromolecular Chemistry and Physics 199 (1998), S. 169-173 
    Details
    ISSN: 1022-1352
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The synthesis of the bis(4-fluoro-2,6-dibromophenolato)bis(pyridine)copper(II) complex was achieved from aqueous solution, and its characterization was performed by means-of IR and CHN elemental analysis. Thermal polymerization of this complex was carried out in toluene and in solid state. The structural analysis of the polymers was performed with 1H NMR, 13C NMR and FTIR analysis; the glass transition temperature was found to be at 160°C. 4-Fluoro-2,6-dibromophenolate, with the non-chelating ligand pyridine, displays selectivity in favor of 1,2-catenation.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 5
    Electronic Resource
    Electronic Resource
    Effect of molecular weight on the refractive index increments of polystyrene, poly(ethylene glycol), poly(propylene glycol), and poly(dichlorophenylene oxide) in solution (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 23 (1985), S. 925-931 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The variation of refractive index increments with molecular weight has been studied using solutions of polystyrene (2.2 × 103 〈 Mw 〈 1.8 × 106), poly(ethylene glycol) (1.0 × 103 〈 Mw 〈 2.0 × 104), and poly(dichlorophenylene oxide) (3.3 × 103 〈 Mw 〈 4.8 × 105) in toluene and poly(propylene glycol) (1.2 × 103 〈 Mw 〈 4.0 × 103) in benzene. The refractive index increments of polyglycols containing aliphatic ether moieties are negative in these solvents. However, poly(dichlorophenylene oxide) polymers, which contain aromatic ether moieties, give positive values. Linear and branched halogenated poly(phenylene oxide)s show an asymptotic approach of the refractive index increment to the same limiting value, but the approach is more rapid for the branched polymer.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1985.180230507
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    Paper (German National Licenses)
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