ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
A prominent ortho interaction occurs during the mass spectral fragmentation of di(2-nitrophenyl)sulphides. No such effects are observed for the corresponding ethers or 2-(2-nitroanilino)thiophens. Variation of aromatic substituents can dramatically alter the effect. Examination of analogous sulphone, sulphoxide, and disulphide molecules, implicates the involvement of the ortho nitro substituent and the sulphur atom in this rearrangement.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210140313
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