Electronic Resource
Weinheim
:
Wiley-Blackwell
Angewandte Chemie International Edition in English
2 (1963), S. 11-20
ISSN:
0570-0833
Keywords:
Displacement reactions
;
Stereochemistry
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Recent interest in the stereochemistry of displacement reactions involving second row elements has led to rapid advances in the preparation and resolution of asymmetric phosphorus compounds. The changes in optical activity accompanying substitution at an optically active phosphorus atom, the reactivity of cyclic phosphates, and the mechanism of intramolecular decomposition reactions involving a phosphorus centre are discussed in terms of the electronic structure of possible transition states.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.196300111
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