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  • 1955-1959  (13)
  • 1958  (13)
  • Chemical Engineering  (13)
  • Engineering
  • pharmacokinetics
Material
Years
  • 1955-1959  (13)
Year
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 249-256 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The rate of absorption of nitrogen peroxide into water at 25° and 40°C. has been found to be a linear function of the concentration of nitrogen tetroxide in the gas phase and directly proportional to the interfacial partial pressure of the same species.The rate of absorption is independent of gas velocity over a range of ReG from 170 to 350. The results plotted as absorption rate divided by interfacial partial pressure of nitrogen tetroxide show no effect of liquid rate or contact time between gas and liquid over a tenfold range of contact time from 0.03 to 0.3 sec. This indicates that the rate-controlling step during nitrogen dioxide absorption into water is the rate of hydrolysis of nitrogen tetroxide.The absorption rate decreases with increasing temperature from 25° to 40°C., owing to the shift of the equilibrium in the gas phase away from the reacting species nitrogen tetroxide toward nitrogen dioxide and owing to the the decreased solubility of nitrogen tetroxide in water. The effect of these factors on absorption more than offsets the effect of the increase in reaction rate and higher diffusivity on absorption at 40°C.The reaction rate constant for the hydrolysis of nitrogen tetroxide has been determined and the solubility of dissolved but unreacted nitrogen tetroxide in equilibrium with gaseous nitrogen tetroxide has been found.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 170-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Virtually all filtration literature has been concerned with constant rate or constant pressure with greater emphasis on the latter. In contrast to these types of operations, industrial filtrations involving centrifugal pumps are accomplished under variable-pressure - variable-rate conditions. In spite of its importance virtually no work has been reported in connection with variable-rate - variable-pressure filtration. Formulas developed for constant pressure and constant-rate filtration are not in general applicable to operations effected by centrifugal pumps. Methods solving variable-pressure - variable-rate filtration problems are presented.A method of determining average filtration resistance as a function of compressive pressure under variable-pressure - variable-rate conditions is discussed, and formulas for determining point filtration resistance from data for average resistances are presented.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 97-101 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 460-464 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The radial variation of void fraction in randomly packed beds of spheres, cylinders, Raschig rings, and Berl saddles was investigated. After packing, the beds were filled with paraffin, which was then allowed to solidify. Slabs were cut from the bed, and annular rings were removed by two different experimental techniques. An analysis of experimental error revealed that reproducibility, for the sample size used, between different parts of the same bed and different beds was quite good.For highly irregular shapes such as Berl saddles results indicate that the void fraction decreases regularly from one at the wall to the average porosity at about 1 particle radius from the wall. This is in agreement with work of other investigators using irregularly shaped packings; most commercial packings would probably fit in this category.For regularly shaped particles results are quite different. For spheres and cylinders cycling was observed for more than 2 particle diam. into the bed, the amplitude decreasing as distance from the wall was increased. The maxima and minima were observed at integral multiples of the particle radius. For Raschig rings a hump was observed at about 1/2 particle radius from the wall. The void fraction then decreased to its average value at 1 particle radius and then remained constant.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 494-494 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 269-272 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Regular-solution equations developed by Hildebrand and others are useful for obtaining semiquantitative estimates of phase equilibria in nonpolar systems. These equations, however, do not take into account the volume change on mixing and therefore require modification for solutions of gases in liquids. The required modifications are presented in this paper, and the resulting equations give reasonable estimates of the solubilities of gases and of the temperature coefficient of solubility. In the modified form the regularsolution theory may be used to estimate gas-liquid phase equilibria at high pressures.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 218-222 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this theoretical analysis of heat transfer in film condensation the total vapor-side resistance to heat transfer is obtained by adding the resistance to conduction through the condensate film to the resistance due to the condensation process at the vapor-liquid interface.The analysis shows that under ordinary conditions conduction in the condensate film is controlling, provided the condensation coefficient is greater than about 0.10. However, under conditions of low total pressure, low heat flux, or low condensation coefficient, the resistances of both processes must be considered.Experiments carried out on the condensation of methanol are in good agreement with the theory. Furthermore, values of the condensation coefficient for methanol are reported which show that small quantities of air will greatly reduce its magnitude. This is offered as an explantion of the commonly observed phenomenon of reduction of heat transfer rates when noncondensable gases enter a system.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 263-265 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The unconventional behavior of equilibrium ratios and convergence pressures is illustrated for close-boiling systems with activity coefficients exceeding 1 throughout the two-phase region. Also presented is a correlation to predict convergence pressure, or the critical locus, of nonideal binary systems.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 4 (1958), S. 14M 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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