ISSN:
0001-1541
Schlagwort(e):
Chemistry
;
Chemical Engineering
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
Notizen:
The phase behavior of the methane-carbon dioxide system has been determined experimentally along the solid-liquid-vapor locus. Pressure-temperature measurements were made along this locus from the triple point of carbon dioxide to -284°F. Compositions of the vapor phase along the solid-liquid-vapor locus were determined with sampling techniques over a composition range of 0.1 to 12% carbon dioxide. Liquid-phase compositions were obtained from crystal-point determinations on eleven methane-carbon dioxide mixtures ranging from 0.16 to 20% carbon dioxide.With the pressure-temperature for the solid-liquid-vapor locus as the termination locus of the dew and bubble data of Donnelly and Katz (2), consistent liquid- and vapor-phase compositions were obtained over the remaining concentration range.Changes in the pressure-temperature relationship of the solid-liquid-vapor locus caused by using a methane stock containing 0.56 mole % nitrogen are also reported.
Zusätzliches Material:
4 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/aic.690080423
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