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  • 1960-1964  (38)
  • 1850-1859
  • 1963  (38)
  • Chemical Engineering  (38)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 365-370 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 485-490 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Reaction-rate measurements were made for the ortho-para hydrogen conversion at -196°C. at 1 atm. pressure with nickel oxide catalysts using alumina and silica gel as carriers. Data were obtained for fine particles for which pore-diffusion resistances were negligible, for large particles of silica catalysts containing only micropores, and for alumina pellets containing both micro- and macropores. From these data experimental effectiveness factors were evaluated.Theoretical effectiveness factors predicted by using a previous theory (7) agreed well with the experimental results. The application of the theory requires pore-geometry data. The measurement of these data and their use in predicting diffusion resistances are illustrated by experimental data and calculations for the several catalysts. It is shown that a satisfactory method of predicting the significance of diffusion within porous catalysts requires information on the pore volume and pore sizes.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 766-770 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Entrance-region studies, based on static-pressure measurements, were carried out with water flowing in annuli and a circular tube fitted with interchangeable square or rounded entrance sections. The tests covered the Reynolds number range from 16,000 to 70,000. For the annuli, the length of duct required to approach to within 5% of the fully developed pressure gradient was about 20 to 25 hydraulic diameters. This is in general accord with entrance length results for circular tubes and parallel-plate channels but differs from prior results for the annulus which had indicated entrance lengths larger by a factor of ten. The results for the sharp entrance showed a definite effect of separation and were characterized by high loss coefficients. For the rounded entrance, the initial part of the flow development was laminar; the entrance-region pressure drop did not substantially exceed (and in one case was less than) the corresponding fully developed pressure drop. Also for the rounded entrance, flow stability was improved and a monotonically decreasing pressure gradient obtained when a turbulent boundary layer was induced by means of a trip. Fully developed friction factors were calculated and compared with theory.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 30-34 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Brine-air and kerosene-hydrogen systems were used for the mixed phase tests. No specific gas phase effects were detected. The measured variability, encompassing all three flow mechanisms, correlated well with particle Reynolds number for each system and decreased with increasing flow rate. However the variability component resulting solely from bulk liquid flow through the main bed channels was found to be relatively constant over a wide range of Reynolds number and independent of whether the bed was uniformly packed or contained large packing faults. The significance of these results to liquid-solids contacting efficiency is discussed.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 85-88 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 129-133 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A digital computer model of the adiabatic-fixed bed catalytic reactor is developed which includes axial dispersion of heat and mass, interparticle heat and mass transport, and intraparticle diffusion of reacting species. The influence of these transport processes upon conversion and yield is discussed. The model is readily extended to nonisothermal, nonadiabatic cases in the absence of radial gradients.The technique of computer solution avoids the inherent instability problem associated with explicit techniques as applied to flux boundary condition problems which involve flow, diffusion, and reaction.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 342-347 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Steady state constant pressure diffusion measurements were made on a series of alumina pellets using the nitrogen-helium system at 1 atm. and 80°F. The pellets were prepared from the same alumina powder but compressed to different densities. Pore size distribution data indicate that all the pellets had approximately the same micropore sizes and volume, but different macropore volumes. Flow measurements with nitrogen were also carried out for the same pellets over a pressure range, up to 1 atm. The data show that the pellet density, or macropore volume, has a pronounced effectOn the basis of a simplified model of the pellet, path lengths were evaluated from the flow data. On the assumption that the diffusion path length is the same, a method is presented for predicting diffusion rates. The results so computed are independent of the path tortuosity. The method correctly evaluates the effect of pellet density on diffusion, but measured rates are 40 to 80% of the calculated values.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 386-390 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 516-523 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow of a highly rarefied gas in a parallel-plate channel and the transfer of heat owing to simulataneous thermal radiation and free-molecule convection has been investigated analytically. The analysis is facilitated by analogies which exist between the processes. The mass throughflow has been determined as a function of the temperatures and pressures of the system and of the channel dimensions. The heat transfer analysis is first carried out in general and then specialized to the boundary conditions of uniform wall temperature, uniform wall heat flux, and the adiabatic wall. It was found that at temperature levels corresponding to room temperature and above, the results for the combined convective-radiative transport differed little from those for a purely radiative transport.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 9 (1963), S. 630-635 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Interphase mass transfer between carbon dioxide gas and water has been investigated. The physical model used was the laminar concurrent flow of gas and liquid in a wide rectangular channel. Because of the high aspect ratio employed, the model was effectively one of parallel plates of infinite width.Three methods of solving the equations of change - the eigensolution method, the boundary layer theory, and penetration theory - were used to compute the diffusion coefficient of carbon dioxide in water from the experimental data. Calculated values of diffusion coefficients from the penetration theory checked well with those from the eigensolution method, but the values computed from the integrated boundary layer equation were about 10% higher.Results from the eigensolution agreed within 5% with the data of other investigators in the temperature range of 20° to 30°C.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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