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  • 1970-1974  (6)
  • 1900-1904
  • 1971  (6)
  • Polymer and Materials Science  (3)
  • Inorganic Chemistry  (2)
  • Organic Chemistry  (1)
Material
Years
  • 1970-1974  (6)
  • 1900-1904
Year
Keywords
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 10 (1971), S. 1351-1364 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The swelling behavior of gelatin gels containing proteoglycans (sulphated proteoglycans from bovine intervertebral discs and a hyaluronate proteoglycan from bovine synovial fluid) when immersed in osmotically active solutions of dextran have been measured. The presence of the proteoglycans markedly affects the internal osmotic contribution to the swelling pressure of the gel. These internal osmotic pressures are considerably in excess of the sum of the osmotic activities of the individual components. This behavior is understood in terms of an entropic interaction between the gelatin and the proteoglycan molecules. By use of the “dilute solution” treatment of Flory, the osmotic pressure excesses are related to the volumes and hence dimensions of the interact acting species. A comparison of these values with those calculated by other means shows good agreement. The osmotic behavior of the complex gels can be understood on a mechanistic basis, if we regard the gelatin and sulphated proteoglycans as spheres and the hyaluronate proteoglycan as a rod.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 1-3 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Glycosides of Amino Sugars, III. Synthesis of Strophanthidin-3-(3′-amino-3′-deoxy-β-D-glucopyranoside)3-Amino-3-deoxy-1.2;5.6-di-O-isopropylidene-α-D-glucofuranose was transformed into the bromide 5 which in a Koenigs-Knorr reaction with strophanthidin yielded the β-glycoside.
    Notes: 3-Amino-3-desoxy-1.2:5.6-di-O-isopropyliden-α-D-glucofuranose wurde in das Bromid 5 übergeführt und dieses in einer Königs-Knorr-Reaktion mit Strophanthidim zum β-Glykosid umgesetzt.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 104 (1971), S. 1976-1980 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Di- and Polyamino Sugars, XVI. Synthesis of 2.3.4.6-Tetraamino-2.3.4.6-tetradeoxy-D-galactoseBenzyl 2-acetamido-2-deoxy-α-D-glucopyranoside was converted into the corresponding allo derivative which was trimesylated and reacted with sodium azide in phosphoric tris-(dimethylamide). After deblocking the free sugar was isolated as its crystalline tetrahydrochloride.
    Notes: Die Synthese der Titelverbindung erfolgte aus Benzyl-2-acetamino-2-desoxy-α-D-glucopyranosid über die entsprechende allo-Verbindung, in die nach Trimesylierung die Stickstoff-Funktionen mit Natriumazid in Hexamethylphosphorsäuretriamid eingeführt wurden. Nach Entfernung der Schutzgruppen wurde der Zucker als Tetrahydrochlorid kristallin isoliert.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 22 (1971), S. 987-987 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Biopolymers 10 (1971), S. 35-46 
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The swelling behavior of gelatin gels when immersed in buffer or in osmotically active solutions of dextran 500 has been studied, and the results can be described by means of the Flory-Rehner theory of the thermodynamic properties of three-dimensional network structures. The density of crosslinkages formed in the gel is found to be related to the concentration of gelatin at which gelation occurs. Values of rigidity moduli are estimated from the density of crosslinkages by use of the statistical thermodynamic theory of rubber elasticity. These values are in excellent agreement with direct measurements.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 54 (1971), S. 77-89 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The crystal and molecular structure of nickel(II)-1, 8, 8, 13, 13-pentamethyl-5-cyano-trans-corrin chloride has been determined by X-ray analysis. The shape and dimensions of the corrin nucleus are discussed in some detail.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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