ISSN:
0449-296X
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The synthesis of optically active p-sec-butylstyrene (I) has been carried out starting with (S)-2-phenylbutane (II) having optical purity 88-91%. The optical purity of I thus obtained was found to be 73-75%. The polymerization of I with stereospecific coordinated anionic catalysts gave amorphous polymers, as in the case of many other p-substituted styrene derivatives. The fractions obtained from these polymers have very similar rotatory power at 589 nm which is practically equal to that of polymer of I obtained by nonstereospecific radical initiator and of low molecular weight structural models. Accordingly the 1Lb electronic transition of the aromatic chromophore shows a very low rotatory strength in all samples examined. This result is related to the lack in solution of conformations with a predominant single chirality of the main chain of the macromolecules derived from I.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1972.150100316
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