ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Collision induced dissociation of the carbon cage compounds cubane, kepone and mirex breaks the cage structures. The energy available for bond breaking is thus not less than about 9 eV, and the time between energy acquisition and subsequent unimolecular fragmentation is long enough that the available energy can be concentrated in three bonds to the same carbon atom. Collision induced dissociation mass-analyzed ion kinetic energy spectra of [C5Cl6]+· from mirex and from hexachlorocyclopentadiene are virtually identical, and similar for [C6H6]+· ions from cubane and benzene.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210150902
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