ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Carbosilylated phospha-alkenesLithium-tris-trimethylsilylmethanide, (Me3Si)3C-Li, reacts with various organodichlorophosphines to give tris-(trimethylsilyl)-methyl-organochlorophosphines, the termal treatment of which under elimination of trimethylchlorosilane results in formation of the title compounds of the general formula B.NMR-data as well as the synthesis of compounds A and B will be discussed.
Notes:
Lithium-tris-trimethylsilylmethanid, (Me3Si)3C-Li, reagiert mit verschieden substituierten Organyldichlorphosphinen zur Tris-Trimethylsilylmethyl-organylchlorphosphinen A, deren thermische Beanspruchung unter Abspaltung von Trimethylchlorsilan zu den Titelverbindungen der allgemeinen Formel B führt.Die NMR-spektroskopischen Daten der Verbindungen des Typs A und B sowie deren Synthese wer-den diskntiert.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19814730209
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