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Redox cationic polymerization: The diaryliodonium salt/ascorbate redox couple (1981)

Crivello, J. V. ; Lam, J. H. W.

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Chemistry Edition 19 (1981), S. 539-548

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ISSN: 0360-6376

Keywords: Physics ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Strong Brønsted acids are produced on reduction of diaryliodonium salts containing anions of the type BF4-, AsF6-, PF6-, SbF6- by ascorbic acid and its derivatives in the presence of catalytic amounts of copper salts. The cationic polymerizations of cyclohexene oxide, tetrahydrofuran, and s-trioxane were studied using the diaryliodonium salt/ascorbate redox couple.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1981.170190227

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