ISSN:
0030-4921
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
This paper reports the 77Se NMR chemical shifts of 1,3-dithiole-, 1,3-thiaselenole- and 1,3-diselenole-2-ones, -thiones and -selones, of the corresponding saturated compounds 1,3-diselenolane-2-one, -thione and -selone, and the 1,3-thiaselenolium tetrafluoroborates, either unsubstituted or substituted by morpholino, ethylthio or ethylseleno groups in the 2-position. The 77Se chemical shift values of the ring selenium and the C=Se groups are compared with the 13C chemical shift values of neighbouring carbon atoms. The relationships between the 77Se chemical shifts of the C=Se groups and the wavelengths of their n→* absorption in the UV-visible spectrum are discussed with respect to the significance of the δE term in the contribution of the paramagnetic screening and the electron density distribution.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1270220803
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