ISSN:
1612-1112
Keywords:
Enantiomeric olefins
;
Platinum complexes
;
Ligand exchange
;
Preparative gas chromatography
;
Preparative column-liquid chromatography
;
Column switching
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Diastereomer formation by the reaction of chiral olefins with optically active platinum complexes followed by LC separation of the diastereomers, and on-line or off-line release of the olefins from the complexes by ligand exchange yield optically pure enantiomers. The 100% dextrostetatory enantiomer of exo-2-vinylbicyclo[2.2.1]heptane (vinylnorbornane) could be isolated by an off-line method and was used for polarimetric measurements before and after preparative scale gas chromatographic clean-up. The initial valuable platinum complex could be easily recovered without loss.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02258766
Permalink
