ISSN:
1572-8854
Source:
Springer Online Journal Archives 1860-2000
Topics:
Geosciences
,
Physics
Notes:
Abstract The title compound is prepared from 1-methylimidazoline-2(3H)-thione (mimtH) and copper(II) chloride, in a 1∶1 mole ratio in methanol. The crystals are monoclinic, space groupP21/n, witha=8.530(2),b=14.258(2),c=9.693(2) Å,β=93.15(2)°,Z=2. The molecular structure shows a dimeric copper(II) complex, in which each copper is chelated by a 1,1′-dimethyl-2,2′-diimidazolylsulfide ligand, and bonded to three chlorine atoms, two bridging and one terminal. The coordination geometry of each copper is approximately square pyramidal, with two nitrogen atoms, a terminal chlorine, and one of the bridging chlorines forming the square plane. The second bridging chlorine forms the apex of the pyramid.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01181261
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