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  • 1985-1989  (7)
  • 1980-1984
  • 1986  (7)
Material
Years
  • 1985-1989  (7)
  • 1980-1984
Year
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 19 (1986), S. 1284-1285 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 19 (1986), S. 2146-2149 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 42 (1986), S. 365-368 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 42 (1986), S. 368-371 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 543-553 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A systematic design of the classical “coat hanger” die is proposed and tested experimentally. The objectives of the design are 1. distribution of the polymer over the width of the die before it reaches the final lip section for thickness adjustment, 2. invariance of distribution to flow rate, 3. invariance to changes in polymer viscosity, and 4. uniform average residence time. The die design is based on a flow model which assumes power-law viscosity, steady shear flow In each cross-section, uniform temperature, and separation of the flows into a manifold component and a component in a slit section of uniform height. The design corrects for an oversimplification of the pressure gradient that was applied in previous studies; and it differs from previous designs by suggesting a rectangular cross-section for the manifold. Applications to side-fed dies for extrusion blow molding and to a sheet extrusion die achieved uniform distribution and did not require any additional flow corrections (such as choker bars or flexible lips). With the new design, the lip region of the die can freely be used for thickness control, fine tuning, or further shaping of the extrudate.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1012-1019 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinematics of ideal welding flows generated by a thin-plate divider, a cylinder, or a slab in a slit channel are studied by using a finite element analysis. The analysis includes simulations of Newtonian and Carreau fluids. There are two flow configurations. First, a single plate-divider or an obstacle was positioned symmetrically in a slit channel with no-slip at the walls. In the second, an infinite number of plate-dividers or obstacles were positioned in parallel, and the boundary walls were infinitely far away. It was found that extensional flow dominates the region near the stagnation points of obstacles and plate-dividers, and that the fluid elements near the weld interfaces have a strain history of both high stretching and shearing. The thickness of the elongated region is reduced as the thickness of the plate-divider increases. Shear-thinning tends to increase the rate of extension. However, its influence on the flow field tends to lessen as the width of the flow channel or the obstacle size increases. A no-slip condition at walls causes slightly stronger elongational flow in the weld interface than does the symmetric condition of perfect slip at walls.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Polymer bulletin 16 (1986), S. 83-88 
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary Extensional flows can induce miscibility in a polymer blend of polystyrene with poly(vinyl methyl ether). Miscibility is observed as a change from turbidity to optical clarity when a phase separated blend flows isothermally in planar extension. In a start-up experiment at temperatures above the LCST, optical clarity does not appear instantaneously but after a time which depends on the rate of extension and the temperature, and it appears first near the region of highest extension. This effect is opposite to the observation for polymer solutions which exhibit shear-induced demixing. We attribute this to the fact that enthalpic effects largely determine blend miscibility, while the phase behavior of solutions is essentially controlled by entropic contributions. Since a deformation field decreases the configurational degrees of freedom of a polymer molecule, demixing is favored in solutions. However, the alteration of specific interactions rather than this entropic effect appears to be much more important in blends.
    Type of Medium: Electronic Resource
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