Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
88 (1988), S. 43-45
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Single crystal EPR of Ni(en)2+3 (en=ethylenediamine) doped in Zn(en)3(NO3)2 is reported. Our results beased on exact diagonalization procedure indicate that the Ni(en)2+3 units undergo distortion along the threefold axis which coincides with the crystallographic c axis. The zero field tensor is found to be axially symmetric with D being 0.831±0.006 cm−1. The utility of S=1 ions in obtaining information regarding molecular distortions is also evidenced.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.454621
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