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  • 1985-1989  (3)
  • 1988  (3)
  • Chemistry  (2)
  • Complex  (1)
  • Inorganic Chemistry  (1)
  • DiGeorge sequence
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  • 1985-1989  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    Die Kristallstruktur eines polynuklearen Co(II)-Komplexes in Cs2[Co3(N3)8] (1988)
    Springer
    Monatshefte für Chemie 119 (1988), S. 509-514 
    Details
    ISSN: 1434-4475
    Keywords: Azide ; Cesium ; Cobalt ; Complex ; Crystal structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Cs2[Co3(N3)8] crystallizes monoclinic,a=1 123.8 (3),b=568.4 (2),c=1 542.6 (4) pm, β=107.37 (2)°, space group P21/n,Z=2. The crystal structure was determined by single crystal X-ray diffraction,R w=0.069. Coatoms are coordinated octahedrally to six azide groups and form polynuclear complexes of composition [Co3(N3)8]2−. The complex anions share edges and are connected to infinite chains running along theb-axis direction. Cesium is irregularly surrounded by azide groups.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00809202
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  • 2
    Electronic Resource
    Electronic Resource
    6-Oxo- und 6-Thioxoverdazyle (1988)
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 121 (1988), S. 815-822 
    Details
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: 6-Oxo- and 6-ThioxoverdazylsA series of persistent 6-oxo- (4a-P) and 6-thioxoverdazyls (5a-g) could be obtained by dehydrogenation of corresponding 1,4,5,6-tetrahydro-1,2,4,5-tetrazin-3(2H)-ones (2a-p) and thiones (3a-g). This reaction can also be used for the preparation of diradicals, e.g. 7 and 10. Reduction, oxidation, and spectra of the radicals were investigated. The ESR results are discussed in detail.
    Notes: Eine Reihe beständiger 6-Oxo- (4a-p) und 6-Thioxoverdazyle (5a-g) konnten durch Dehydrierung der 1,4,5,6-Tetrahydro-1,2,4,5-tetrazin-3(2H)-one (2a-p) bzw. der Thione (3a-g) erhalten werden. Diese Reaktion läßt sich auch auf die Darstellung von Diradikalen, z.B. 7 und 10, übertragen. Reduktion, Oxidation und Spektren der Radikale wurden und Spektren der Radikale wurden Untersucht. ESR-Ergebnisse werden eingehend diskutiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cber.19881210502
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  • 3
    Electronic Resource
    Electronic Resource
    ENDOR and triple resonance studies of 1,4-dihydro-1,2,4-benzotriazinyl radicals and 1,4-dihydro-1,2,4-benzotriazine radical cations (1988)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 26 (1988), S. 595-600 
    Details
    ISSN: 0749-1581
    Keywords: ENDOR ; Triple resonance spectroscopy ; 1H NMR ; 1,4-Dihydro-1,2,4-benzotriazinyl radicals ; 1,4-Dihydro-1,2,4-benzotriazine radical cations ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ESR, ENDOR and triple resonance studies of 1,4-dihydro-1,3-diphenyl- (1a) and 3-tert-butyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazinyl (2a) and of the corresponding radical cation 3a (2a protonated at N-4) yielded the magnitude and the sign of almost all of the 1H and 14N hyperfine coupling (HFC) constants. Their assignment was performed using various 2H labelled and/or methyl substituted derivatives. Both radical groups show major hyperfine coupling to the three 14N nuclei. In the uncharged species 1a and 2a, the spin density at N-4 apparently directs the 1H HFC pattern in the 1,2,4-benzotriazinyl component, a(H-5) and a(H-7) being larger than a(H-6) and a(H-8). In the radical cation, on the other hand, N-1, with an unusually large splitting of 9.9 G, is the position of highest spin density which determines the 1H HFC pattern, a(H-6) and a(H-8) being larger than a(H-7).
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1260260712
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    Paper (German National Licenses)
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