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  • 1
    Book
    Book
    U.S :Mathematical Association of America,
    Title: Mathematical writing; Vol. 14
    Author: Knuth, Donald E.
    Contributer: Larrabee, Tracy , Roberts, Paul M
    Publisher: U.S :Mathematical Association of America,
    Year of publication: 1989
    Pages: 115 S.
    Series Statement: MAA Notes Series Vol. 14
    Type of Medium: Book
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 54 (1989), S. 958-965 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Analytical chemistry 61 (1989), S. 535-539 
    ISSN: 1520-6882
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 90 (1989), S. 880-887 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We prove that Liapunov functions for a single reactive intermediate evolving toward a nonequilibrium steady state can be obtained from a global potential φ. We consider reactions occurring in a chamber containing a reactant, the intermediate, and a product. Reservoirs connected to the chamber serve to hold the reactant and product concentrations constant, in nonequilibrium proportions. The Liapunov property of φ is significant because of the role it plays in the thermodynamic and stochastic analysis of nonequilibrium systems: φ is defined in terms of the reactive flux to produce the intermediate and the flux to remove the intermediate. The derivative of φ with respect to the concentration of the intermediate yields an effective chemical driving force that is specific to the intermediate, and its time derivative yields a species-specific component of the dissipation that is minimized at steady states. These results hold both near to equilibrium and far from equilibrium for systems with one intermediate, independent of the number of steady states. Local Liapunov functions are also provided by the "excess dissipation,'' the second variation in the entropy or in the Helmholtz free energy for the reaction chamber, and quadratic functions introduced in Keizer's fluctuation–dissipation theory. Linearization of the force and flux expansions for nonequilibrium systems yields an idealized model in which the dissipation decreases monotonically in time and thus provides a Liapunov function for evolution to steady states. This result does not hold for a chemical system approaching a steady state with an arbitrarily small, but macroscopic displacement from equilibrium, even though the series expansions of the reactive fluxes and conjugate thermodynamic forces are closely approximated by truncation at the linear terms. There are always small regions in the immediate vicinity of nonequilibrium steady states where the dissipation increases in time while the system relaxes.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 91 (1989), S. 6282-6289 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We present the optical anisotropy of a hard sphere suspension subjected to combined electric and shear fields. We model the particle structure factor as a shear induced perturbation of the anisotropic structure induced by electric field. We renormalize the nonconvergent birefringence integral to allow calculation of birefrigence from the particle structure factor. The principle axes of the birefringence and dichroism tensors vary with the Mason number, a measure of the relative strength of shear forces to electric dipole interaction forces. The principle axes only coincide in the shear dominated and the electric field dominated limits. The magnitudes of birefringence and dichroism are sensitive to the particle size relative to the wave-length of light employed. We compare theoretical predictions in the limit of pure shear to the experiments of Wagner et al., J. Chem. Phys. 89, 1580 (1988), employing a simple affine deformation theory for the structure factor, which yields fair agreement with experiment for the dichroism but poor agreement for the birefringence. The prediction of optical properties provides both a test for theories of microstructure and insight into the effects of shear and electric fields on microstructure.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 28 (1989), S. 1634-1641 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Biochemistry 28 (1989), S. 8537-8542 
    ISSN: 1520-4995
    Source: ACS Legacy Archives
    Topics: Biology , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 60 (1989), S. 2768-2776 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: Rotary kiln systems are widely used in industrial applications to transfer energy from high temperature flames to irregular solids. Recently these systems have been shown to be suitable for the incineration of hazardous solid waste materials and the thermal treatment of contaminated soils. Destruction and removal efficiencies in excess of 99.99% have been reported for hazardous species, but the rate controlling steps of the incineration process are not well understood. This article describes the design, construction, and operation of a laboratory scale simulator which was developed to investigate the fundamentals of hazardous incineration in a rotary kiln environment. This 2 ft×2 ft refractory-lined kiln allows time-resolved characterization of contaminant evolution and destruction. Continuous thermal and exhaust concentration measurements are used to characterize the fate of the solid charge as a function of residence time within the kiln. Overall destruction efficiency can be measured by subsequent analysis of the solid phase. The initial performance of this facility has been demonstrated by studying the combustion of waste zirconium metal and by characterizing the thermal clean up of solid sorbent contaminated with toluene. The rotary kiln simulator has been shown suitable for investigation of parameters such as amount of charge, contaminate loading, rotation speed, temperature, excess oxygen, and particle size.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1469-8986
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine , Psychology
    Notes: Physiological measures were taken from 7 closed-head-injured patients and 7 control subjects while they took a series of cognitive tests: the finger tapping test from the Halstead Reitan battery, the Digit Symbol test from the WAIS-R, a test of logical memory, and a paced arithmetic test. Physiological reactivity was assessed relative to rest periods, which occurred at the beginning and end of each session. The tests and physiological assessment were administered twice, approximately one month apart. The patient group performed more poorly on the cognitive tests, and showed less physiological reactivity during them than did the control group. This pattern was statistically significant for heart rate, frequency of electrodermal responses, and, during the initial session, respiration rate. The control group also showed greater finger pulse amplitude during the first posttest rest period in the first session, and greater constriction during a logical memory task in the second session. No significant between-groups differences emerged for state or trait anxiety. The patients showed higher frontalis EMG and respiration rate during rest. These results suggest a pattern of poor physiological modulation for task performance in the patients with closed head injuries. The therapeutic implications are discussed.
    Type of Medium: Electronic Resource
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