ISSN:
0021-8995
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The anionic solution polymerization of butadiene was studied employing both batch and continuous reactor operations with n-butyllithium (n-BuLi) initiator, tetramethylethylenediamine (TMEDA) modifier, and hexane solvent. A model was proposed that described the kinetics as a function of both the fully modified and unmodified regressed rate data. Using the proposed kinetic model, the conversion, vinyl structure, and heterogeneity index of polymers produced for a series of continuous runs were successfully predicted. The model was used to simulate several process configurations.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/app.1990.070391115
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