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High-pressure Raman study of liquid and solid ethanol at pressures up to 17 GPa (1990)

Shimizu, H. ; Nakamichi, Y. ; Sasaki, S.

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 21 (1990), S. 703-704

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: High-pressure Raman spectra of liquid and solid ethanol were measured at pressures up to 17 GPa and 300 K in a gasketed diamond anvil cell. The frequencies of in-phase and out-of-phase O—H stretching vibrations which characterize the hydrogen bond along the zig-zag chain decrease with increasing pressure with slopes(dν/dP) of -14.3 and -12.4 cm-1 GPa-1, and they overlap with the CH stretching mode at about 11 and 17 GPa, respectively. No solid-solid phase transition was observed at pressures up to 17 GPa.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250211012

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