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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 28 (1990), S. 963-971 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Diffusion coefficients of camphorquinone (CQ) and its photoproduct (CQP) in two poly(methyl metbacrylate) (PMMA) samples with different molecular weights are measured as a function of temperature. Above the glass transition, the temperature dependence is not Arrhenius and can be described by the Williams-Landel-Ferry equation. It is also shown that the difference in the temperature dependence of the diffusion coefficients of CQ in the two PMMA samples is attributable to the difference in glass transition temperatures.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electroanalysis 2 (1990), S. 81-84 
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A new nicotine sensor for the simple, rapid determination of nicotine in tobacco products without prior separation is described. The sensor is a coated graphite electrode with silicotungstic acid as the active material in polyvinyl chloride with di(2-ethylhexyl) phthalate as the plasticizer. At pH 5.5-6.0, it provides a Nernstian response to nicotine over 10-1 to 10-6 M; the detection limit is 7.4 × 10-7 M, and the average slope is 58 mV/pN. The analytical recovery is 98.1 to 102.3%. Satisfactory results are obtained in comparison with silicotungstate gravimetric method and UV spectrometry.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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