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Photofragmentation of cluster ions: the visible photoabsorption spectrum of Ar2N 2 + (1991)

Nagata, T. ; Kondow, T.

Springer

The European physical journal 20 (1991), S. 153-155

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ISSN: 1434-6079

Keywords: 36.40 ; 33.80 ; 33.20

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The absolute cross section for photodissociation of Ar2N 2 + was measured as a function of wavelength in the 470–550 nm range. A structureless broad band was observed; the cross section has a maximum of ∼ 210 × 10−18 cm2 at ∼ 500 nm. The measurement of the photofragment time-of-flight spectrum shows that(1) N 2 + , Ar+ and Ar 2 + are produced in the photodissociation of Ar2N 2 + in the wavelength range studied, and that(2) the observed visible absorption band is ascribable to a parallel-type transition of Ar2N 2 + , which possibly retains a linear geometry.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01543961

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