Library

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 397-404 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A reasonable analytical procedure of the overall reaction rate for the phase transfer catalysis with mass transfer is discussed. Alkaline hydrolysis of n-butyl acetate with a phase transfer catalyst Aliquat 336 (tricaprylmethylammonium chloride, Q+Cl-) was chosen as a model system and carried out in an agitated vessel with a flat interface. Overall reaction rates observed were proportional to the interfacial concentration of the actual reactant Q+OH- (the ion pair consisting of quaternary ammonium cation Q+ and OH-) for the hydrolysis in the organic phase. The interfacial concentration of Q+OH- was a unique function of bulk concentrations of the catalyst and NaOH, and the ionic strength of the aqueous solution. This behavior of the overall reaction rates was explained by the proposed model solution. The reaction rate constant, evaluated by fitting the rate data to the model prediction, was 47 m3/kmol·s at 298 K. It was 70 or more times greater than that of conventional alkaline hydrolysis in the aqueous phase.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 879-886 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A new type of fluidized bed, called a circulating fluidized-bed adsorber (CFBA), was developed for processing a large quantity of water with high efficiency. Its fluid mechanical characteristics are reported, as well as recovery of uranium from natural seawater using a small CFBA. Using hydrous titanium oxide, granulated with polyacrylonitrile (PAN-HTO), as an adsorbent, CFBA ran stably for six days, the period required for the adsorbent to collect a practical amount of uranium. To predict the uranium adsorption performance of a plant-size CFBA, a numerical model simulating the adsorption kinetics was developed. The result of the numerical calculation by the model was in good agreement with the experimental data.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 1667-1670 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...