ISSN:
0887-6266
Keywords:
cellulose/NH3/NH4SCN system, lyotropic mesophases of
;
phase equilibria in cellulose/NH3/NH4SCN system, mesophase occurrence in
;
anisotropic and mesophase formation in cellulose/NH3/NH4SCN
;
Solvent systems
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Mesophase formation of the cellulose/NH3/NH4SCN system has been studied as a function of system composition at 25°C. Compositions for incipience of mesophase formation and for wholly anisotropic phase formation have been determined and relevant phase diagrams constructed. The biphasic gap narrowed when the solvent composition approached 75.5 weight percent NH4SCN and as the cellulose concentration decreased. As solvent composition was changed, the minimum cellulose volume fraction for mesophase formation ranged between 0.02 to 0.045.
Additional Material:
4 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/polb.1992.090300401
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