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  • 1990-1994  (3)
  • 1992  (3)
  • Chemistry  (3)
  • epoxy
  • phase lag
Material
Years
  • 1990-1994  (3)
Year
Keywords
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 44 (1992), S. 1631-1634 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The X-ray absorption coefficients of carbon fibers, different polymeric matrix materials, and composites were measured and the fiber contents in the composites were calculated from the measured absorption. In addition the fiber content determinations were performed by means of acid digestion of the polymeric matrix and weighing. Good agreement was found between the results obtained by the two different methods. The experimental error in the fiber content measurements was determined as a function of the difference in the coefficient of the matrix material and the fiber.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 45 (1992), S. 399-406 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermoanalytical measurements and tack tests were both performed using a commercially available carbon fiber/epoxy prepreg system (Hercules 3501-6) to examine changes caused by aging as they affect handling and processability of thermosetting matrix-based composites. Combining these techniques, a relationship between prepreg bulk and surface characteristics in relation to aging was investigated. Isothermal kinetic studies at low temperatures showed maximum conversions (αm) that increased with increasing cure temperatures. In addition, a linear relationship between glass transition temperatures (Tg) and conversions (α) was observed regardless of aging (or cure) temperatures. Energy of separation of prepreg stacks, which may be viewed as a measure of prepreg tack, showed a maximum value at a specific temperature. The maximum energy of separation was observed in the temperature range of 20-25°C above the glass transition temperature for a given sample. However, the maximum energy of separation values decreased with increasing aging times (or conversions), implying that prepreg tack was a viscoelastic property rather than a viscous property of the resin matrix in the prepreg.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 13 (1992), S. 197-206 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: As part of an engineering analysis and experimental methodology to characterize prepreg tack, a compression-to-tension test was optimized to enhance reproducibility and generate intrinsic property data. With the resulting stress-strain compression and tension data, a theoretical model was developed to describe tack as a bulk viscoelastic property of a prepreg laminate stack. Using the viscoelastic analysis, four intrinsic material parameters to characterize prepreg tack could be defined. These were 1) relaxed modulus, 2) unrelaxed modulus, 3) relaxation time, and 4) initial void content of the prepreg stack. Relaxed and unrelaxed moduli of the prepreg stack were independent of temperature, while the relaxation time was highly dependent on temperature and matrix viscosity. In addition, the relaxation time was found to be influenced by resin/fiber content and prepreg surface characteristics, which also influenced the void content of the prepreg stack. Using these measured parameters, good agreement was observed between theory and experimental data for both the stress-strain curve of the tack test and the simplified compression tack index (CTI*), defined as the ratio of output energy of the prepreg stack during tensile unloading to input energy during compressive loading.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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