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  • 1990-1994  (1)
  • 1890-1899
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  • phase transition  (1)
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    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 897-900 
    ISSN: 0044-2313
    Keywords: High pressure x-ray diffraction ; compressibilities ; phase transition ; Zintl phases ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thermal Dilatation and High Pressure Behaviour of the Zintl Phases CaSn und BaSnData on the thermal dilatation and the compressibility of the compounds CaSn and BaSn are derived from x-ray measurements performed at high temperatures and high pressures in a diamond anvil device. At higher pressures BaSn undergoes a transition from the CaSi- to a CsCl-type structure. The field of existence in P and T is determined from the in situ measurements.
    Notes: Aus röntgenographischen Untersuchungen mit einem Diamant-squeezer unter währenden hohen Drücken und Temperaturen werden Daten zur thermischen Dilatation und zur Kompressibilität der Verbindungen CaSn und BaSn abgeleitet. BaSn geht bei höheren Drücken vom CaSi- in den CsCl-Typ über. Der Existenzbereich der beiden Modifikationen im Feld von P und T wird aus den in situ Untersuchungen abgegrenzt.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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