ISSN:
0009-2940
Keywords:
Ferrocene derivatives
;
1,1-Ethenedithiolate complexes
;
Group 10 metal complexes
;
Heterodimetallic compounds
;
Heterotrimetallic compounds
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The ferrocenyl-substituted mono- (3) and 1,1′-bis-dithiocarboxylic acids (4) have been prepared. These acids react with L2MCl2 (M = Pd, Pt; L = PEt3, PPh3, and 1/2 dppe) in the presence of sodium acetate to give the cis heterodi- and heterotrimetallic complexes cis-L2M[S2C=CH—C(O)-(η5-C5H4)Fe(η5-C5H5)] (5a: M = Pd, L = PPh3; 5b: M = Pt, L = PPh3; 5c: M = Pt, L = 1/2 dppe) and [cis-L2MS2C = CH—C(O)-(η5—C5H4)]2Fe (6a: M = Pd, L = PPh3; 6b: M = Pt, L = PEt3; 6c: M = Pt, L = PPh3; 6d: M = Pt, L = 1/2 dppe). The structures of 5a and 5b have been determined by single-crystal X-ray diffraction.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19941270105
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