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  • 1990-1994  (3)
  • 1994  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical crystallography 24 (1994), S. 75-78 
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract A reinvestigation of the X-ray crystal structure of malonic acid (C3H4O4) has been made in the light of some observations arising from solid-state13C NMR studies on this compound. The unit cell parameters are:a=5.156(1),b=5.341(1),c=8.407(1) Å, α=71.48o (2), β=76.12o (2), γ=85.09o (2), space group $$P\bar 1$$ ,Z=2. The structure was solved by direct methods and refined by full-matrix least-squares refinement to a finalR value of 0.038 for 711 unique reflections withl〉3σ. The packing of the molecules involves dimeric hydrogen bonded association of each carboxyl group with a centrosymmetrically related neighbor. The angles O−C−O (123.3o and 124.8o, respectively) for the two carboxyl groups agree qualitatively with the values predicted from a linear relationship relating the observed σ22 component of the Carbon-13 NMR chemical shielding tensor for the carboxyl carbon atom to the bond angle O−C−O at the carbon atom.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Nutrient cycling in agroecosystems 37 (1994), S. 69-78 
    ISSN: 1573-0867
    Keywords: fertilizer efficiency ; partially acidulated phosphate rocks ; permanent pastures ; phosphate rock
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Phosphate rocks partially acidulated either with H3PO4 or H2SO4 were compared against SSP or TSP as phosphate fertilizers for permanent pasture. Eleven field trials were conducted over periods of up to 6 yrs. Fertilizers were surface applied annually. Initial soil pHw values ranged from 5.5–6.3 and Soil P retention from 25% to 97%. The PRs used for partial acidulation were unground or ground North Carolina PR, ground Khouribga PR, and a blend of ground PRs of North Carolina, Arad and Khouribga PRs. From the DM yields, fertilizer substitution values were calculated: fertilizer substitution value was the ratio of total P applied as superphosphate to total P as PAPR required to produce the same DM yield. Rates of dissolution of the PR component of PAPRs were also determined in soils collected from two trials. Agronomic results demonstrated that 30% acidulated phosphoric PAPRs (about 50% of total P as water-soluble P) were as effective as TSP, when the PR acidulated was from unground North Carolina PR. Results from one field trial indicated that when PAPR was from ground North Carolina PR, 20% acidulated product (water-soluble P 30–40% of total P) was equally effective as TSP. Replacement of ground North Carolina PR by a less reactive Khouribga PR did not appear to decrease the yield. Results indicated that per unit P released into soil solution, PAPRs were more efficient fertilizers than TSP. With annual applications, fertilizer substitution value of PAPR 30% tended to increase with time. Sulphuric PAPRs prepared from North Carolina PR were generally inferior to phosphoric PAPRs containing similar amounts of water-soluble P. This was attributed to the presence of CaSO4 coatings.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 50 (1994), S. 827-829 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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