ISSN:
1042-7163
Keywords:
Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Treatment of tetrakis(triphenylphosphine)platinum with elemental selenium (red or vitreous) in toluene solution under reflux yields an insoluble solid. This dissolves in dichloromethane with reaction, eventually to form a 1 : 1 mixture of [PtCl2(PPh3)2] and the new compound [Pt(Se2CH2)(PPh3)2], which has been characterized by multinuclear NMR spectroscopy and X-ray crystallography. Under the same conditions, tetrakis(triphenylphosphine)-palladium yields only decomposition products. © John Wiley & Sons, Inc.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hc.520060606
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