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  • 1995-1999  (3)
  • 1975-1979
  • 1905-1909
  • 1995  (3)
  • polymer blends  (2)
  • Brassica  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Developmental regulation of aldoxime formation in seedlings and mature plants of Chinese cabbage (Brassica campestris ssp. pekinensis) and oilseed rape (Brassica napus): Glucosinolate and IAA biosynthetic enzymes (1995)
    Springer
    Planta 196 (1995), S. 239-244 
    Details
    ISSN: 1432-2048
    Keywords: Aldoxime biosynthesis ; Auxin biosynthesis ; Brassica ; Glucosinolate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The first steps in the biosynthesis of glucosinolates and indole-3-acetic acid (IAA) in oilseed rape (Brassica napus L.) and Chinese cabbage (Brassica campestris ssp. pekinensis) involve the formation of aldoximes. In rape the formation of aldoximes from chain-extended amino acids, for aromatic and aliphatic glucosinolate biosynthesis, is catalysed by microsomal flavin-containing monooxygenases. The formation of indole-3-aldoxime from l-tryptophan, the potential precursor of both indole-3-acetic acid and indolyl-glucosinolates, is catalysed by several microsomal peroxidases. The biosynthesis of glucosinolates and indole-3-acetic acid was shown to be under developmental control in oilseed rape and Chinese cabbage. No monooxygenase activities were detected in cotyledons or old leaves of either species. The highest monooxygenase activities were found in young expanding leaves; as the leaves reached full expansion and matured the activities decreased rapidly. The indole-aldoxime-forming activity was found in all of the tissues analysed, but there was also a clear decrease in foliar activity with maturity in leaves of rape and Chinese cabbage. Partial characterisation of the Chinese cabbage monooxygenases showed that they have essentially identical properties to the previously characterised rape enzymes; they are not cytochrome P450-type enzymes, but resemble flavin-containing monooxygenases. No monooxygenase inhibitors were detected in microsomes prepared from either cotyledons or old leaves.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00201380
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Drop deformation during elongational flow in blends of viscoelastic fluids. Small deformation theory and comparison with experimental results (1995)
    Springer
    Rheologica acta 34 (1995), S. 525-533 
    Details
    ISSN: 1435-1528
    Keywords: Emulsion model ; polymer blends ; drop deformation ; elongational flow ; viscoelasticity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Abstract The deformation of dispersed droplets in immiscible polymer blends was studied in elongational flow, with an original method based on quenching specimens elongated in the melt. Results for high capillary numbers and different viscosity ratios were compared to the linear theory of viscoelastic emulsions of Palierne. Simple expressions for the drop deformation could be obtained for Maxwell fluids, and the influence of viscoelasticity of matrix and inclusions on the drop deformation process was discussed. With respect to the Newtonian approximation, the description of some experimental data could be improved. However, the predictions of the viscoelastic model appeared to be very sensitive to the choice of relaxation times.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00712313
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Relationship between structure and rheological properties in the melt of polymers containing spherical inclusions (1995)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 6 (1995), S. 301-308 
    Details
    ISSN: 1042-7147
    Keywords: polymer blends ; melt rheology ; crosslinked rubber ; structured latex ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The linear viscoelastic behavior of model rubbertoughened polymer melts has been studied. The most significant influence of the dispersed crosslinked rubber phase on the melt rheology of the blends is the existence of a secondary plateau for the storage modulus G′ at low frequencies. This behavior was ascribed to a percolation phenomenon, leading to the formation of a threedimensional network of inclusions, and contributing to the elasticity at low frequencies of the blend. Two different systems were investigated: (a) a polystyrene matrix with crosslinked and structured latex particles and (b) silicon oil matrices with homogeneous crosslinked PMMA particles. An initial shearing history was found to influence the dynamic mechanical properties of the molten blends and in particular to lower the lowfrequency plateau value for G′. During a subsequent annealing, the plateau modulus increases again. These results are in agreement with the assumption of a particle network.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1995.220060508
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    Paper (German National Licenses)
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