ISSN:
1434-6036
Keywords:
75.20
;
72.90
;
61.65
;
76.30.P
Source:
Springer Online Journal Archives 1860-2000
Topics:
Physics
Notes:
Abstract Crystal structure, microwave conductivity and static magnetic susceptibility were analyzed for the conducting perylene (PE) radical cation salts of nominal composition (PE)2(PF6)1−x (AsF6) x ·2/3 THF for 0≦x≦1. Crystallographic phase transitions in the high-temperature metal phase were also characterized by differential scanning calorimetry and electron spin resonance. The Peierls transition occuring at 100–120 K (depending onx) and the opening of the energy gap in the semiconductor phase were determined from the magnetic data. The dependence of these properties on the size of the complex anions and the packing of the PE molecules is discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01313841
Permalink