ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary The cationic polymerization of 1,3-pentadiene (PD) initiated by AlCl3 in n-hexane was carried out in the presence of allylic halides, i.e., 3-chloro-1-butene, allyl chloride, and allyl bromide. All these allylic halides strongly hindered crosslinking which is a major side reaction during PD cationic polymerization. Cyclization, another side reaction, was also reduced by the addition of the allylic halides. The influences of these halides on polymer yields and molecular weights are also discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00315061
Permalink
