ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
Inelastic neutron scattering has been performed on CHD3 molecules matrix isolated in solid argon. Four inelastic lines have been observed within the energy transfer range 0≤(h-dash-bar)ω≤2.5 meV. The corresponding energy level scheme and the line intensities are explained in terms of a model based on a completely free rotation of the CHD3 molecule. An expression for the double differential neutron scattering cross section of the free CHD3 rotor is derived. In spite of a line shift of 44% with respect to the free rotor, no crystal field splitting was observed. © 1996 American Institute of Physics.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.472051
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