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  • 1995-1999  (3)
  • 1970-1974
  • 1965-1969
  • 1997  (3)
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  • 1995-1999  (3)
  • 1970-1974
  • 1965-1969
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Catalysis letters 47 (1997), S. 99-103 
    ISSN: 1572-879X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Isomerization of heptane was carried out at 573 K under atmospheric pressure using molybdenum oxides as catalysts. MoO3 was inactive for this reaction. H2 reduction of MoO3 at 623 K, however, enhanced the isomerization activity and selectivity, which became almost constant after the reduction for 24 h. The reduced MoO3 exhibited a higher isomerization activity than a typical bifunctional catalyst, 0.5 wt%Pt/USY zeolite, while there was no appreciable difference in product distribution between these two catalysts. These results indicate that the reduced MoO3 catalyzed the isomerization of heptane via a conventional bifunctional mechanism.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 218 (1997), S. 103-105 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract We studied the solvent extraction behavior of astatine and found the anomalous behavior of this element similar to radioiodine. Astatine was extracted into CS2 from acidic solution over a wide range of carrier iodine concentration. The distribution ratios of astatine were determined by measuring the γ-ray from 210 At with a Nal(TI) detector. A drastic change was observed around at 10−4 mol/l as in the case of 131 I. This tendency is well explained by the kinematics of the chemical reactions concemed.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of radioanalytical and nuclear chemistry 223 (1997), S. 99-119 
    ISSN: 1588-2780
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The role of the charge degree of freedom in the heavy-ion-induced fission was investigated by carrying out a systematic analysis of radiochemically observed charge distribution in the fission of238U with12C ions of the incident energy between 85 and 140 MeV, particularly in connection with the energy given to the compound system. The charge distribution was found to follow essentially identical systematics as those which govern the light-ion fission except for the extremely weak energy dependence of the most probable chargeZ p. That is, values of the derivative ofZ p with respect to the energy were found to be quite small, or nearly zero, in the heavy-ion fission as compared to those of the light-ion fission. According to an analysis combining the derivatives ofZ p and fission neutron data, it was deduced that the excess energy given to the fused system was spent completely in the form of pre-scission neutrons and hence the number of post-scission neutrons remained constant as in the case of light-ion fission. The observed charge distribution was reproduced under the conditions that the relaxation of the charge degree of freedom be very fast and that the separation between the two potential fragments at the moment when the charge degree of freedom has been frozen is determined by usingViola's systematics on the fragment kinetic energy.
    Type of Medium: Electronic Resource
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