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  • 2000-2004  (2)
  • 1990-1994
  • 2001  (2)
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  • 2000-2004  (2)
  • 1990-1994
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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 89 (2001), S. 859-868 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Simultaneous measurement of the absolute optical absorption coefficient or species concentration, thermal diffusivity, and flow velocity in a gaseous medium has been demonstrated by using pulsed photothermal deflection spectroscopy (PTDS) and a multiparameter fitting procedure. The spatial distribution of the three parameters in a laminar flow has been simultaneously determined and the influence of velocity gradient on the measurement has been discussed. Saturation behavior of the PTDS signals was observed and found to influence significantly the fitted results. The saturation influences most significantly the absorption coefficient determination, somewhat less significantly the thermal diffusivity determination, and only negligibly the flow velocity determination. For an absolute and accurate measurement of the absorption coefficient or species concentration, the saturation-induced error has to be corrected by using a model taking into account the effects of the saturation. The influence of saturation on the thermal diffusivity determination can be significantly accounted for by using a simple model in which the pump beam radius is set as a free parameter in the multiparameter fitting procedure. Both multipulse and single-pulse measurements are performed. For multipulse measurement, the estimated measurement uncertainties are ±2% for the flow velocity, and ±5% for the thermal diffusivity and absorption coefficient, while for single-pulse measurement, the estimated uncertainties are ±2% and ±10%, respectively. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 78 (2001), S. 4136-4138 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Thin films (9 μm) of polyvinylidene fluoride (PVDF) are irradiated by swift heavy ions (180 MeV Ag14+) in the fluence range 1×1010–1×1012ions/cm2 with an electronic linear energy transfer LET∼11 keV/nm. In sharp contrast to the previous results, the most characteristic crystalline asymmetric and symmetric "CH2" doublets (located at 3025 and 2985 cm−1), have shown remarkable increase in their respective Fourier transform infrared (FTIR) absorbance intensities upon low fluence ion impact (1010 ions/cm2). This increase in absorbance is in consonance with the simultaneous decrease of the transmission intensities of other crystalline bending vibration bands located at 532 (CF2 bending), 614, 796, and 975 cm−1 (all due to CH2 bending) at the similar ion fluence. It appears most probable from the results that, being a polar polymer, the molecular dipoles in PVDF forming a hydrogen bond network get realigned upon irradiation into a highly ordered state of chain molecules in the crystalline regions and create volume elements as crystallites. © 2001 American Institute of Physics.
    Type of Medium: Electronic Resource
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